Faculty

Institution

Unit

Venue

Dave Collum

Professor

Cornell University

Affiliations

College of Arts and Sciences

Department of Chemistry and Chemical Biology

Dave Collum is currently serving as a College Of Arts And Sciences Professor at Cornell University.

Honors

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Experiences

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Education

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Dave Collum

Cornell University

Professor

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chemistry organic chemistry structural chemistry chemical structure organometallic chemistry chemical sciences molecular structure chemical synthesis biochemistry organic process research physical organic chemistry organic synthesis biomolecular engineering enantioselective synthesis molecular chemistry organic chemistry frontier inorganic chemistry chemical engineering transition metal chemistry coordination chemistry supramolecular chemistry stereoselective synthesis asymmetric catalysis physical chemistry heterocycle chemistry main group chemistry lithium diisopropylamide synthetic chemistry altmetric attention score organometallic catalysis structure elucidation lithium hexamethyldisilazide spectra-structure correlation mixed aggregates computational studies molecular complexes physicochemical analysis solution (chemistry) inorganic compounds general chemistry chemical analysis heterocyclic energy chemistry reactivity (chemistry) sodium diisopropylamide chemical physics organometallic electrochemistry social media presence lithium enolates molecular science halogenation continuous variation chemical thermodynamics combinatorial chemistry organometallic polymer novel organocatalysts lda dimer rate studies sodium hexamethyldisilazide mixed aggregation material chemistry dalton transaction lithium-ion batteries coordination complex molecular aggregate alkene metathesis cross-coupling reaction lithium chloride catalysis donut icon nmr spectroscopy inorganic chemistry frontier magnetic resonance deep eutectic solvents macromolecular chemistry theoretical inorganic chemistry energy storage materials chemical kinetics

Video Presentations

Notable Scholarly Works

Notable Federal Grants

Collaborators

An Accidental Synthetic Chemist. Synthesis (2025)

David Collum

organic chemistryenantioselective synthesisorganic synthesisbiomolecular engineeringsynthetic chemistrychemical scienceschemistrysolvation influence reactivitychemical synthesisaccidental synthetic chemistorganic process research

Potassium Isopropyl(Trimethylsilyl)Amide and Potassium Tert -Butyl(Trimethylsilyl)Amide: Solvent-Dependent Solution Structures and Reactivities. Organometallics (2025)

Jesse A. SpiveyDavid B. Collum

organic chemistrychemical derivativemolecular structurebiomolecular engineeringstructural chemistrychemical sciencesorganometallic chemistrychemistryinorganic chemistrychemical structureorganometallic catalysissynthetic chemistrypotassium isopropylchemical synthesisorganic process research

Potassium Hexamethyldisilazide (Khmds): Solvent-Dependent Solution Structures. Journal of the American Chemical Society (2024)

Jesse A. SpiveyDavid B. Collum

inorganic compoundspotassium hexamethyldisilazideputative ion paircoordination chemistrymolecular structurecoordination complexsupramolecular chemistryion pairsstructural chemistryorganometallic chemistrychemistryinorganic chemistrychemical structuremolecular complexesmolecular chemistrybiochemistry

Potassium Isopropyl(Trimethylsilyl)Amide and Potassium Tert-Butyl(Trimethylsilyl)Amide: Solvent-Dependent Solution Structures and Reactivities. (2024)

Jesse SpiveyDavid Collum

physicochemical analysisdft computationsspectra-structure correlationmolecular structuresupramolecular chemistrydimeric whereas kbtastructural chemistrychemical sciencesorganometallic chemistrychemistrymolecular chemistrychemical structurepotassium isopropylsolution (chemistry)biochemistry

Sodium Alkyl(Trimethylsilyl)Amides: Substituent- and Solvent-Dependent Solution Structures and Reactivities. Journal of the American Chemical Society (2024)

Qiulin YouYun MaRyan A. WoltornistNathan M. LuiJesse A. SpiveyIvan KeresztesDavid B. Collum

solvent-dependent solution structuresorganic chemistrychemical derivativesodium isopropylderivative (chemistry)organic synthesisbiomolecular engineeringstructural chemistrychemical sciencesorganometallic chemistrychemistrysynthetic chemistrychemical structuresodium alkylchemical synthesisorganic process research

Carbon–Nitrogen Bond Formation Using Sodium Hexamethyldisilazide: Solvent-Dependent Reactivities and Mechanisms. Journal of the American Chemical Society (2023)

Qiulin YouDavid B. Collum

organic chemistryenantioselective synthesissodium hexamethyldisilazidecomputational studiesmolecular structureorganometallic chemistrychemistryorganic process researchmolecular chemistrysolvent-dependent reactivitybiochemistry

Sodiated Oppolzer Enolates: Solution Structures, Mechanism of Alkylation, and Origin of Stereoselectivity. Organic Chemistry Frontiers (2023)

Nathan M. LuiDavid B. Collum

organic chemistryenantioselective synthesissolution (chemistry)stereoselective synthesisoppolzer enolatesmolecular structuresodium camphorsultam enolatesbiomolecular engineeringstructural chemistrychemistrychemical structurecurious solvation effectsorganic chemistry frontierchemical synthesisorganic process research

Sodium Isopropyl(Trimethylsilyl)Amide: A Stable and Highly Soluble Lithium Diisopropylamide Mimic. The Journal of Organic Chemistry (2022)

Yun MaNathan M. LuiIvan KeresztesRyan A. WoltornistDavid B. Collum

organic chemistryphysicochemical analysisphysical organic chemistrysodium isopropylphysical chemistrymolecular structuretrans stereoisomeric dimersdensity functional theorystructural chemistrychemical sciencesorganometallic chemistrychemistryinorganic chemistrychemical structuremolecular chemistrybiochemistry

Aggregation and Solvation of Sodium Hexamethyldisilazide: Across the Solvent Spectrum. The Journal of Organic Chemistry (2021)

Ryan A. WoltornistDavid B. Collum

organic chemistrysodium hexamethyldisilazidedft computationscoordination chemistrymolecular structuresupramolecular chemistrybiomolecular engineeringstructural chemistrychemistryinorganic chemistryorganometallic chemistrychemical structuremolecular complexesstandard solvents

Ketone Enolization With Sodium Hexamethyldisilazide: Solvent- and Substrate-Dependent E – Z Selectivity and Affiliated Mechanisms. Journal of the American Chemical Society (2021)

Ryan A. WoltornistDavid B. Collum

organic chemistryasymmetric catalysisenantioselective synthesisphysical organic chemistryketone enolizationsodium hexamethyldisilazidesitu enolate trappingmolecular structureorganic synthesisbiomolecular engineeringchemical sciencesorganometallic chemistrychemistryorganic chemistry frontierchemical synthesisorganic process research

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Dave Collum

Professor

Cornell University

Affiliations

College of Arts and Sciences

Department of Chemistry and Chemical Biology

Dave Collum is currently serving as a College Of Arts And Sciences Professor at Cornell University.

Honors

Create free account to unlock more features

Experiences

Create free account to unlock more features

Education

Create free account to unlock more features

Dave Collum

Cornell University

Professor

You can click a keyword to filter the displayed items

Video Presentations

Notable Scholarly Works

Notable Federal Grants

Collaborators

An Accidental Synthetic Chemist. Synthesis (2025)

David Collum

Potassium Isopropyl(Trimethylsilyl)Amide and Potassium Tert -Butyl(Trimethylsilyl)Amide: Solvent-Dependent Solution Structures and Reactivities. Organometallics (2025)

Jesse A. SpiveyDavid B. Collum

Potassium Hexamethyldisilazide (Khmds): Solvent-Dependent Solution Structures. Journal of the American Chemical Society (2024)

Jesse A. SpiveyDavid B. Collum

Potassium Isopropyl(Trimethylsilyl)Amide and Potassium Tert-Butyl(Trimethylsilyl)Amide: Solvent-Dependent Solution Structures and Reactivities. (2024)

Jesse SpiveyDavid Collum

Sodium Alkyl(Trimethylsilyl)Amides: Substituent- and Solvent-Dependent Solution Structures and Reactivities. Journal of the American Chemical Society (2024)

Qiulin YouYun MaRyan A. WoltornistNathan M. LuiJesse A. SpiveyIvan KeresztesDavid B. Collum

Carbon–Nitrogen Bond Formation Using Sodium Hexamethyldisilazide: Solvent-Dependent Reactivities and Mechanisms. Journal of the American Chemical Society (2023)

Qiulin YouDavid B. Collum

Sodiated Oppolzer Enolates: Solution Structures, Mechanism of Alkylation, and Origin of Stereoselectivity. Organic Chemistry Frontiers (2023)

Nathan M. LuiDavid B. Collum

Sodium Isopropyl(Trimethylsilyl)Amide: A Stable and Highly Soluble Lithium Diisopropylamide Mimic. The Journal of Organic Chemistry (2022)

Yun MaNathan M. LuiIvan KeresztesRyan A. WoltornistDavid B. Collum

Aggregation and Solvation of Sodium Hexamethyldisilazide: Across the Solvent Spectrum. The Journal of Organic Chemistry (2021)

Ryan A. WoltornistDavid B. Collum

Ketone Enolization With Sodium Hexamethyldisilazide: Solvent- and Substrate-Dependent E – Z Selectivity and Affiliated Mechanisms. Journal of the American Chemical Society (2021)

Ryan A. WoltornistDavid B. Collum

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